If you are hesitant reticent when handling a snake they sense this and it makes them defensive and jumpy, too.
You should show no fear. That is why it is best to start with the babies. You must expect to get bitten every time you handle a snake like that.
If the snake is too large, or you're just not comfortable with it, I'd suggest you move on to what you feel comfortable with.
Of course there are a multitude of other reasons a snake like that might be grumpy. No security, no humidity, retained shed, mites, enteritis, dehydration, too hot, too bright, respiratory, Stomatitis.
As long as the snake's physiological and psychological husbandry needs are met they should calm down.
You might try leaving a t-shirt or some other clothing with your scent on it in with the snake.
That's all my ramble.
jsc
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"As hard as I've tried, just can't NOT do this"
John Crickmer

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