I'm no expert, but I'll give answers as best I know, and the others will fill in and correct any misstatements.
>>Are they usually arboreal?
Yep, Yellows and many other ratsnakes spend a lot of time off ground. Most obsoleta subspecies do, as they regularly dine on birds and their eggs.
>>Do they hold up well in captivity?
Yep. Once you get it acclimated to feeding on frozen/thawed rats/mice, they usually don't look back. They are relatively long-lived (20 yrs?) and good feeders and producers.
>>And how is a yellow different from an everglades rat snake? Are they different species, subspecies or varieties?
Lots of controversy here, but generally, the 'glades is considered a redder variety of yellow ratsnake, and there is certainly scientific speculation that all the ratsnakes in the range (East of the Appalachians?), whether black, grey, greenish, yellow, or orange, are all the same subspecies, in different clothing.
P.S. - If your large ratsnake is a female, there's a chance its gravid at this time of year.
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...and I think to myself, "What a wonderful world."