As far as what tpye of concrete to use, look on the labels, any thing saying anything about containing VOC's, stay away from... Portland Cement mix is a good bet, so is the quick crete line ( yah just gotta know where exactly you want it with that stuff, it hardens really fast... ) After you lay your concrete, wet cure it, ( cover with paper towel or burlap in your case due to the size of your project ) and allow the water to cycle for around 30 days. I contacted the Quick-crete head office, and they said after 30 days all the chemicals will leach out of the concrete. Once the 30 days is up, then seal and re-cycle the water... change the water out weekly so the chemicals don't build up in the pond, I know with a project the size your talking about, that's not gonna be fun!! Any ways... best of luck... hope this helped...
Yes I realize my project that I posted is no where near the size of yours... but I have help build coy pond and turtle ponds as well, and used the same technique...
And when in doubt... test the water... any good fish store will have all the testing kits you'll ever need to make sure it's safe for your aquatically dependant friends...

