Coppper compounds are used in the dairy industry all the time, and I assure you that copper in enough quantity is more poisonous to cows than it would be to humans due to the way they digest.
As a matter of fact, 2 different chemicals are designed to stop the digestive action of the rumen to allow access to the next stomach for medicines that would be dangerous if allowed to enter the rumen.
One of them is a designed copper overdose, IIRC. The overdose is administered WITH the antidote, dolomite. Otherwise known as a 'drench'. It also kills most of the worm burden in the gut as well. Another, more common is a relative of anti-freeze, glycol.
Copper sulfate is prolly the most used compound to prevent foot rot, though applied topically.
Most cows are given copper as a suppliment in their feed to avoid poisioning them with a copper overdose when the gut burden becomes severe. Ounce of prevention, pound of cure sort of thing.
As to if it would be poisonus to rodents, I doubt it.
Would it be poisonous to SNAKES, quite possibly.
I would avoid using copper compounds, until you have confirmation that it's ok.