Research is my thing. I'm not about to kill my animals by acting foolhardy and jumping into something I don't understand. I know this is rare, but it's me. Seems like you feel the same way there that I do, where you like to see the scientific fact to back up opinion (I'm referring to the d3 issue here, where neither of us want to hear, "don't do it", but want to hear "dont do it because..."
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So, the pH thing isn't a mystery. But, would it not lower eventually? Would it really leech out forever?
This site is really reading intense, but it's one of the better ones I've found for using cement. It has some first hand experiences with cement in aquaria, and some of the chemistry behind things. http://www.reefs.org/library/talklog/t_miller_052498.html He talks about some of the curing & everything involved, and that's another of the sites that says about it curing indefinitely & becoming stronger in water.
Here's another that says about a specific aquarium-safe cement.
http://www.thekrib.com/TankHardware/concrete.html
I don't know where I'd be able to find Thorite, but I am looking into it. They say in there that Thorite works, but on Thoroseal's website, there's a mention of mixing something else into Thorite in high-moisture areas.
The big item in question, now that you've pointed out about cichlids liking high pH is this- absolutely everything says, "pH will return to normal in ___ days." None of them say what normal is. It could be quite possible that normal does mean high.
And finally, my intentions for the cement have been primarily for aquarium use. I was wanting to combine the cement with other things (chunks of slate, other stones and all that), and make some naturalistic setings for in my aquarium. Make a wall of rock caves on one end and all that. Silicone won't quite work as well for what I'm thinking, because I want big rocks. So, the whole reptile thing is a byproduct- if I bought cement & used it in the aquarium, I'd have stuff left over. Figured I might as well use it for other cages.
I'm thinking I might test this out. I could get a bag of cement for $3. It wouldn't be the exact stuff I'm going to use, but it would at least give me an idea of what the final pH would be, after curing. I could mix together a chunk, and dispose of the rest- it'd still be a cheap enough experiment. Or, I could probably hit up the local Vocational Technical school, and see if I could just have a cup of the dry cement.
Thank you so much for the information here, I really do appreciate it. If this starts to get lost, and we're still sharing information, feel free to hit me up with an e-mail. I'd rather not blare it through here, where random searches can find it, but send me a PM or e-mail through the site & we could go from there.