How long have you had them, and do you know how old the male is? It really does seem like a territorial thing with the female and all. Collareds are iguanidae... ya know, like igunanas, and I haven't had a collared bite me but I can give you an iguana story. Maybe they think they same way and this will help:
Our friends had a huge, sweet male iggy named Cream Puff. I was visiting my friends for Easter and went out to visit Cream Puff. I approached the cage slowly speaking sweetly, he understood I wasn't a threat, came to the door... I picked him up, he was nuzzling, all was good. He got heavy so I set him down. I was sitting on the ground with my hands on either side of me, knees bent... he walked under my legs and gave my left hand a very weird look... and before I could finishing thinking "This doesn't look good..." he had clamped down across my index and middle fingers. I heard a god awful crunch and foolishly tried to pull my hand away, ripped my fingers open. I thought he crushed my hand, but no broken bones. I was on the highest doses of Cipro and Augmentin that I could handle for 2 weeks, had to have a hand surgery to remove 2 teeth and still don't have all the feeling in my left index finger (this was nearly 3 years ago).
(moral of the story... i tell long stories) But anyway, there was an escaped pet male that had taken up residence in the neighbor's yard. To this day, we aren't certain why Cream Puff bit me, but we always thought he was getting territorial towards the other male and took it out on me.
This maybe be slightly discouraging, but he bit another friend of theirs in the upper arm about a year later so maybe it has nothing to do with the neighboring male... maybe he was just becoming an angry old man. 
Maybe that helps...? I'll spare you guys the gory post bite pics... 
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"Were the diver to think upon the jaws of the shark, he would never lay hands on the precious pearl."