Oil-based finishes cure in two stages. First is the solvents flash off leaving a hardened skin on the surface. Once these solvents have flashed off a exothermic reaction takes over which relys on oxygen. This oxygen is inhibited by the surface film that forms when the solvents flash off. Due to this the solvents in the middle of the film layer are somewhat trapped and take a long time to offgas.
With modern VOC restrictions companies have been forced to reduce the amount of solvents in their products. What happens is that the average user ends up appying these products too thick and the problems described above are made even worse.
I do believe that oil based products could still be used in a reptile cage but only if they were applied in a way very different than recommended.
Typically the finishing schedule or urethane means that subsequent coats are applied during a tight window where the previous coat is somewhat cured but still at a point where the next coat can burn in. I think you can see how this would really affect the problems I have already described. Not only is the original surface film impeding the curing process, but now the second, third, etc, coats are impeding that even further.
What I would do is to thin down the urethane with a solvent and wipe it on as thin as possible. And instead of applying the next coat during that tight window of opportunity, I would wait for the coat to fully cure and then apply the next coat. You'd have to scuff sand inbetween coats to allow the next coat to adhere since they could no longer burn or melt into each other.
Obviously this would add an extraordinary amount of time it takes to finish a cage as not only would more coats be required, but a coat could only be applied every couple of weeks, maybe less, maybe more.
But given how long some people wait for cages to offgas, this might not be such a bad thing.
Oil-based urethanes offer an incredible amount of protection for the money. They are cheap and readily available. But even in the hands of the experienced you can end up with a very thick coat with an interior that is basically still soft. Many a talented woodworker has had to spend hours sanding off very gummy urethane in order to salvage an expensive project.
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Current snakes:
0.0.1 Gonyosoma oxycephala - Java locale (green)
1.2 Gonyosoma oxycephala - Jave local (green)
2.2 Gonyosoma janseni - Seleyar locale (all black)
1.2 Gonyosoma janseni - Celebes locale (Black & Tan)