I know this doesn’t have much meaning, however at one point I did incubate two clutches at 84-85 degrees and the hatches were 2.6 and 2.9 which were thayeri and alterna respectively.
The subject of temperature dependent sex determination you’re curious about is an interesting one. As you already know, it’s understood that with some reptiles (crocodilians, most turtles, certain lizards…) hatchling sex determination is primarily environmental, meaning higher incubation temps produce a higher female to male ratio. A while back I dug in to a little research to see what I could come up with relating to sex development in kingsnakes. What I found was nothing conclusive, nothing that I found was specific to kingsnakes, however there does seem to be evidence that suggests higher temps can affect secondary sex determination in at least some egg laying snakes and produce more females. Secondary meaning during egg incubation and the latter stages of development. From what I understand, primary sex determination in most egg laying snakes is believed to be purely genetic… meaning that the sex of the embryo is determined genetically during the initial development while still being carried by the female.
Fairly recently I read a brief article (on livescience dot com) about a study done by the Australian National University concerning global warming and it’s potential effects on life, which was conducted using Bearded Dragons. What they determined was that in ideal incubation conditions for Beardies, an equal mix of male and females developed. When they raised the incubation temps to the higher end of the scale that would still allow the eggs to hatch, significantly more females resulted, indicating that the higher incubation temperature had over-ridden gene-controlled sex determination. They suggest that a gene on the Z chromosome triggers male development and a protein expressed by this gene is temperature sensitive. At high temps this protein becomes less effective and unable to trigger male testis development, and the Beardies develop instead as females with ovaries. The interesting thing about it was that when they analyzed DNA for both normal temp incubated lizards and high temp incubated ones, the phenotype of those incubated at normal temps matched their genetic makeup… males looked like males and females looked like females with regard to their sex organs. However, about half of the lizards from high-temperature incubators had a mismatched make-up, in which genetic males "looked like" females. Male on the inside (genetically), but phenotypically female.
Studies have also shown that egg-bearing snakes that are incubated at slightly lower temps (that take longer to emerge) hatch out longer from snout to vent, have better overall development and motor skills, improved brain development, can raise higher and hold back stronger to strike, and seem overall better suited for survival and being successful.
How much of this do you think could relate to our kingsnakes? Personally from all this I think taking a good middle-of-the-road approach to incubation temps is a good way to go, your decision to go with 80 degrees sounds great to me!

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Mike