Most colubrid snakes (Lampropeltines included) have identifiable sex chromosomes. Sex in these snakes is determined through genetic factors in a system like that used in birds (the ZW system). In this system, it's the females that are homozygous (ZW) and the males that are heterozygous (ZZ). This contrasts the system used by placental mammals (XY system) in which the males are heterozygous (XY) and the females are homozygous (XX).
Current research suggests (strongly...) that any offset in the sex ratio of snake eggs incubated at varying temperatures is purely coincidental. It must be remembered that the probability of a trait (color, pattern, sex, whatever)in a clutch of eggs is for each egg individually - each egg has a 50/50 chance of being either sex. Sometimes an entire clutch will hatch the same sex one year, and the following year the same parents could be bred, their eggs incubated exactly the same way, and all of the offspring could be the opposite sex. Very interesting stuff, and there are lots of great papers published on the subject.
-Cole