Hi,
110 F shouldn't be a problem. I only keep snakes so don't utilize such temps regularly/purposefully but I may expose my polystyrene basking spots to such temps on occasion. Certainly they regularly go a little over 100 (says my temp gun). Probably 4 hrs/day. No site-specific cracking of grout (I cure it carefully). Mine is a little thicker on the horizontal surfaces - no problem with that either. Note I use CFL 14W bulbs about 6" from the highest level of "rock" for my basking points (for terrestrial saxicolous vipers). Air temp doesn't exceed 85F. Something more "spotty" (focused heat) or a steeper air/substrate temp gradient could maybe cause you a headache??? I'm a biologist, not a physicist, bear with me!
Here's the king of fake plants, to me - this guy's proficiency is incredible. Haven't gone there yet, still fussing with fake rock, but someday I'll try to be like Brent:
http://www.bbrock.frognet.org/Making%20artificial%20trees%20and%20vines.pdf
Anyway, hope this helps.
cheers,
Jimi