I can't think of any ratsnakes that I had never heard of back in the '90's, but I do remember when many of them were very uncommon on collections. Heck, it does not seem that long ago that Taiwan Beauty Snakes were uncommon, but I'm showing my age...
A few questions:
What is the rarest of these?
Of the snakes currently in the Eurasian Ratsnake Classifieds, I'd have to say either Elaphe flavolineata or Ptyas korras are the two that seem the least common. I think both are common in their native areas, however. Just not commonly imported.
Any newly described to science & the hobby?
Can't think of any.
Does anyone own any of these?
Of the snakes currently in the classifieds, I have kept Gonyosoma janseni and Rhynchophis boulengeri. I have some short term experience with the Bamboo Ratsnakes and Gonyosoma frenata. Currently only keeping Gonyosoma oxycephala, but those were available back in the 1990's so I doubt you are referring to them.
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Currently keeping:
6.10 Gonyosoma oxycephala (Javan, mixed colors)
1.1 Philodryas baroni
1.0 Rhodesian Ridgeback