ambient temperatures is just that, air temperature. Surface temperatures is the temperature on the surface of an object, not the air above it.
For dragons basking temperature is the surface temp of the basking spot. Warm end of the cage ambient temps should be 80-90F with cool end ambient temps dropping to 70-80F with nighttime temps being 65-70F.
Only two accurate ways to measure surface temp and that is with a temp gun (best) or thermometer with probe, with probe directly on top of the surface. Air temps can be with quality stick on dial type thermometers or the probe suspected midair.
For undertank heaters (which I don't recommend as a heat source for dragons at all) surface temp is the surface right above the heater (basically as close as the dragon could get to the area the UTH is. If underneath a glass tank then it will be the temp on the glass inside the tank. UTH should never be placed inside a cage. UTH should also always be controlled by a proportional thermostat to ensure they don't' get too hot. As most lizards are very poor judges of temperature from their bellies (unlike snakes that are better capable), burning their underside or damaging internal organs is very easy through belly heat.
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PHLdyPayne