Hi Jamie,
It is more likely a polyphemus. The caterpillars of the two look very similar to the untrained eye. The main difference is that the luna's head is green and the poly's brown. The "stripes" on the luna are horizontal and the poly vertical.
Did she just find it wandering? If so, it was looking for a place to pupate, or does she know what it was feeding on? Regardless, I would put some leaves in with it. Both usually wrap themselves in leaves; "naked" pupa often do not survive as the cocoon helps to keep it from drying out. Even if it is beyond that point I would cover it with some dry, freshly picked leaves (maple, oak, etc.) to at least maintain some moisture. Be sire no little critters (spiders, assassin bugs) are on the leaves. You can rinse them then pat dry with paper towel.
MOST IMPORTANT right now is to not move or disturb it. If it gets reoriented from original pupating position it can die or become deformed. Do not touch it as this is a very crucial time. Put the container in a cool, place out of harm’s way. After about 2-3 weeks you can place it in a plastic container on a bed of folded paper towel with ONE DROP of water, then put on the cover. You can store this in the crisper compartment of your fridge until next May or June.
Btw, IF it is a luna it probably got there via an irresponsible hobbyist. Eggs of many species are available worldwide and although people are not supposed to release any that are not indigenous to the area people still do.
Check out my webshots Antheraea polyphemus (link below). I just uploaded some pics of the two species, one side by side. Hope all of this helps and feel free to ask other rearing questions.
lele
lele's pics