You are probably right about the ants, but I think it is still worth a try to order some Western Harvesters and see if he'll eat them. While the Florida Harvester is a Pogo, it is more distantly related to its congeners in the western US than any of them are to each other. P. badius probably split from the ancestral lineage of the North American Pogos long before the species west of the Mississippi speciated. It is very different in many aspects of its biology from other North American harvesters, including the presence of polymorphic workers (only found in P. badius and some South American spp.). Any two of the ~25 species in the West are going to be much more closely related (with one possible exception) to each other than any of them are to the Florida Harvester. So while any Pogo in the Western US is likely to be very similar to any other, this is not so nearly the case for P. badius. Also, P. badius's range does not overlap that of any HL species.
As I said, you are probably right, and his refusal to eat the ants is likely due to stress and habituation to the mealy beetles. I certainly hope you're right, because then I will be able to cut my own dependence on mail-order ants, if I can find some local colonies (I'm unfortunately at the very southern end of their range). However, given the known differences of P. badius compared to the various other North American species of Pogo with which the little fellow is likely to be familiar, it seems like a good idea to at least try a western species. And even if he does prefer a western species to P. badius, it might be possible to wean him from those onto the Florida species, once he's back to comfortably and regularly taking ants again.
Karu, I would still suggest that you try the refrigerator trick, and if that doesn't work, order some of the Western Harvesters. If he'll eat those, then try mixing in some of the Florida ants with the western ones and see if you can "trick" him into taking the Florida ants. This way you might be able to switch him over to those.