Again, I agree with Bill. Charcoal is just another addition in substrate, and once it has absorbed what it can, it is saturated and no longer active. While it doesn't help for long, neither is it harmful. It may continue to add somewhat to the drainage. I use it quite a bit in my sub-drainage however, mixed with the rock and gravel of the bottom drainage system. There's no real reason to do this I suppose, but my grandmother said so, and she always used charcoal from the stove along with the broken crockery on the bottom of her house plant pots, and had could grow anything. Chemically, it is actually short-lived, and as Bill said, needs replacing if it is to continue to be useful for absorbing excess nitrates, etc.
On the other hand, as the substrate becomes leached out, it may have held the excess nutrients that the plants can use later.
These are just thoughts, not advice. In any event, I don't think adding charcoal will do any harm. I still do it, not from any real chemical knowledge about how it acts in this situation, but just because my grandmother said so.
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Patty
Pahsimeroi, Idaho
4 D. auratus blue
3 D. galactonotus pumpkin orange splash back
5 D. imitator
4 D. leukomelas
4 D. pumilio Bastimentos
4 D. fantasticus pending