Well, I'm brand new to the snake thing, but experienced w/ other herps. With my new guy, I lifted the item he was hiding under & lay my hand down near him. He waited a bit, then came over to explore my hand, at which point I picked him up. Seemed to work well for us... 
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1.0 Reverse Okeetee Corn snake Fuzzy
1.3.0 leos, Yoda, Geo, Tang, Ginger
1.0 Blue Tongue Skink Indigo (Indy)
0.1.1 frogs Buffy the Cricket Slayer, Butrose Butrose Froggy
1.1.4 firebelly newts Wayne Newton, Isaac Newton, Fig Newton, Juice Newton, Olivia Newton John & Helmut Newton
1.1.0 cats Gus & Mena
