I'm not sure exactly which species of Psammophis that is (the taxonomy of the genus is rather a mess). However, there's a couple minor details you should be aware of.
They are in a separate family (Psammophiinae) along with other genera such as Malpolon. Their closest neighbors are the snakes in Madagascar (the Psudoxyrhophiinae lineage) and also the Atractaspidae (the stilleto snakes).They are not 'colubrids' even by a conventional, informal definition but rather if a strict decision had to be made between 'colubrid' and 'elapid', the Psammophis are 'Elapids'.
The venom glands are huge (bigger than some elapids) and the venom is actually quite toxic. We rate the larger species as potentially lethal. In particular is mossambica, this is the one that is sold as sibilans, the true sibilans is a dinky little thing.
In anycase, they are very neat snakes and usually settle down well into captivity. Just be aware of the potential for bites and treat them accordingly.
Enjoy 
BGF
Venom & Toxin Database