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kay first of all i want to know if i should use plywood or mdf wood?
Plywood will be lighter than MDF at a given thickness. If you use MDF I'd highly recommend 3/4" (1/2" sags too much). If you use plywood you could use 1/2" if you wanted (see posts below by TTreptile).
If cost savings is your primary concern, use 3/4" MDF. If weight savings is a larger concern, use plywood.
I also find plywood easier to work with.
::and what kind if glue to hold them together?
Regular wood glue and screws.
::also i was wondering, if u coat the inside of the cage with resin,
By resin I assume you mean fiberglass resin?
::do you resin the whole inside before you put all the pieces together?
Overall it's easier to seal the inside of the cage after it is assembled.
::and would i be better off to just cover the inside with those white PVC sheets?
This is generally easier to do, but is more expensive and then you have to make sure your silicone is keeping things water-tight.
::if so, do you have to route the edges at all or anything because they are sharp?
No. The sharp edges of the plastic meet along the edges of the cage and you silicone along this edge.
::and can you hot glue the edges where they meet or is that not necessary?
Something is necessary. Hot glue might actually work well. But I've never tried it. Silicone is the traditional choice.
::and what is the best way for ventilation? just drilling holes in the wood or what is best?
Most people cut holes out of the wood and install ventilation greats or PVC drainage grates. Again, see TTreptiles posts.
::6 feet long X 2-3 feet deep and 3-4 feet high (let me know if you dont agree with those dimensions)
I'm not a Boa guy. Randy T. here on the forum has a lot of cage design experience and keeps a lot of boas. Hopefully he'll respond.
In general Boa enthusiasts don't recommend large (tall) cages due to the difficulty of retaining heat and humidity. Personally, I think your cage is a bit big.
One concern you have with a cage that size is fitting it through doors. Make sure this will work before you build.
I suspect for all but the very largest female Boa constrictors a cage length of 4' is sufficient. It's also cheaper to add floor area by increasing the width (aka depth) of the cage rather than exceeding 4' in length.
But I'm not the right guy to answer that question for you.
For a very large cage I don't believe a UTH will be sufficient. You almost certainly would have to go with radiant heat panels at a minimum.