Well, Raja's setup is currently a 20 L that was vacated recently by two tiger salamanders. He originally (as a baby) was in a 10gallon, but outgrew it before I bought his future home (in a month when I move) of a 40 G Oceanic Chameleon tank, with the screen sides and top. He drinks out of an Exoterra waterfall and has the UV coil bulb and a 75 W dayglo bulb. When he was in the 10 gallon, I had switched to only a 50 W Nightglo all the time because he was constantly distancing himself as far as he could from the bulb and was gaping his mouth a lot, so I figured he was hot. (the temperature in my room is usually between 78 and 80º as it is, without any added heat bulbs). Recently, the temp outside dropped to around 60, and we've left any air conditioning/heat off, so the room temperature is probably closer to 70 and he has been darker in color, so I changed back to the 75 Watt bulb, and he's back to his normal green color.
As for the water, I really dont' know about its chemical makeup, I work in a petstore so I could easily bring home a couple test strips to see howo it balances out. I haven't been using any ReptiSafe though, so I could start doing that if you think the water could be affecting his coloration.