I prefer to use the water-thin product. Then I use masking tape to hold the edges together and inject it along the edge. The solvent wicks into the joint.
You can use cheap corner clamps to hold the very ends of the panels in addition to the tape but they're not absolutely necessary. Still use the tape every few inches after the clamps.
A few tips:
1) Leave the paper wrap on the acrylic except for where the panels will meet. You will almost certainly drip solvent on the panels and it will scar the finish.
2) Prep your edges perfectly. The better prepared they are the less likely small cracks will form along the edges. I believe this is called "crazing". You'll want to avoid crazing.
3) Do an internet search on building acrylic aquaria. There are numerous links. Read as much as you can.
4) Practice as much as possible. If you won't have any scrap acrylic leftover from your project then see if you can get some from glass and plastic shops.