The temperatures are a bit high for darts. 65 at night to 80 during the day is the general range of tolerance for any length of time. 85 seems a bit high. One usually depends upon room temperatures to keep the tanks at the right temperature. If you live in a hot climate and don't have central air conditioning, consider a cooler for the room they are in. I don't have a lot of experience with lowering temperatures, because that isn't the problem here. The lights will heat up a tank. You may want to raise them farther above it, or turn them completely off in hot weather.
I wouldn't worry about what the humidity gauge says. With the misting and fogging, damp substrate, waterfalls, etc. they aren't going to suffer. The humidity gauge is in one location, probably against one end of the tank midway up. It doesn't reflect what is around the frogs. Your frogs can chose their own location depending upon their needs. If you have condensation on the glass, you have high humidity.
As the plants grow, they will also help to stabilize this.
I like to have bromeliads such as Neoregalia that hold water in the axils. All darts, not just the thumbnails that use them to breed, utilize these axils to rest in and soak.
Your set-up sounds great. Please post some pictures. Except for the somewhat high temperatures to be optimum, I think your're all set.
-----
Patty
Pahsimeroi, Idaho
4 D. auratus blue
5 D. galactonotus pumpkin orange splash back
5 D. imitator
6 D. leucomelas
4 D. pumilio Bastimentos
4 D. fantasticus
4 P. terribilis
4 D. reticulatus
4 D. castaneoticus