Six minnows a week isn't too much depending on the size of the snake and minnows. While a youngster you probably can't feed too much, as s/he gets older you can back off a little to keep the snake from getting obese. Waternsakes have a pretty high metabolism so they'll feed more than some species, especially if you keep them adequately warm.
As was mentioned below, you can dust a quallity multi-vitamin once a month or so, not every feeding. I think the biggest mistake regarding water snake care in captivity is that people think they need to be kept in a wet or moist enclosure. But they actually have to have a very dry environment with clean water always available. Dampness will quickly lead to scale rot on their ventral scales and eventually kill the snakes.
Joe
Reptiles and Amphibians of Iowa and Minnesota