My opinion resides with the others that have posted to this thread so far. E. carinatus is probably the hottest, drop for drop, viperid around.
As to your first question, my assumption would be that yes, kings do prey on other venomous species. I believe I have a book or two floating around here saying something to that effect, but finding them would be futile in my unorganized masses of books and papers. They will also eat pythons and small Varanids. Most ophiophagic species, like NA kingsnakes, mussuranas (Clelia clelia), and the many Varanids that make use of venomous snakes as prey, have coevolved a partial to full resistance to those specific animals' venoms. That's not to say, though, that if a kingsnake were to be bitten by an African cobra or a taipan or something while trying to eat it that it'd necessarily be able to survive the venom effects. Immunity has to be specific to the venom, since venoms vary a *huge* amount between species and genera. Just ask anyone to self-immunizes (not recommended). They have to inject multiple species venoms into their systems to build up tolerances to those specific snakes. The same often goes for making antivenoms. So yes, it is reasonable to assume that kings have an immunity to most or all of the venoms of the snakes that cohabitate the area.
Great questions (and no venomoid crap!! lol). I hope there are further, more informed replies...ahem...BGF, WW?
-Chance
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Chance Duncan
http://www.rivervalleysnakes.com