I have been reliably & accurately sexing babies this way for a number of years. with experience it can be done at any stage of the animals maturity...as neonates,(prior to first shed,especially!) baby males have very little control of movement over the vestigal spurs,and,have not developed the slight reccessed "pocket" in which they tend to "retract" them...gently bending their tails to the side,in good lighting,it is quite obvious which ones are little boys,and,which are the little ladies....I have had numerous "females" from "rolling/popping/probing" hobbyists & breeders over the years,that have sired viable litters of babies when placed with "real females!" (*lol* so much for "sure things"! I have considerable experience in sexing a variety of species of snakes,including GTP's,using the popular methods available,& I can't remember the last time I had to dig out my probes for baby boas,nor the last time a customer contacted me,and,said,"Uhhm,guess what?"
In my experience,I feel too much pressure is frequently needed to manually evert the hemipenes with species that have strongly prehensile tails,and,I never rely on the "rolling palp" method by itself,visual confirmation of the lack of cloacal spurs,negates anything I "thought I felt"...just my 2 beans on the issue, "YMMV"