>>I want to construct a few cages from melamine with pegboard backings to cut down on the weight and provide ventilation.
You might scroll down through some recent threads and look at the racks made with 1/8" showerboard for sides. I've used 1/2" plywood for the sides and that saves a lot of weight, the showerboard even more.
If you do use the showerboard I believe the pegboard would be a good idea for the back.
If you don't feel comfortable with the showerboard for the sides then I'd recommend no back at all. Just use some simple cleats to stop the boxes.
Then some Reflectix insulation can be used to insulate the back and reflect that heat back into the boxes.
>>My questions are, would it be safe to attach flexwatt directly to pegboard?
It certainly has been done but that does not mean it's "safe". I really don't care to make a recommendation either way.
>>Would this form of heat (back heat) be suitable for heating my snakes (corns, pines, and a blood python)?
In a cool room, probably not, especially for the blood python. But belly heat is often not suitable either. People still use it and the snakes seem tough enough to deal with it.
Again, you might read through some recent threads to learn more about this.
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Current snakes:
0.2 Gonyosoma oxycephala - (Silver/Yellow)
3.3 Gonyosoma oxycephala - (Green)
2.1 Gonyosoma janseni - (Black)
3.3 Gonyosoma janseni - (Black & Tan)