The thicker stuff is hard to find. I'm building a snake room in my third garage stall and had to go to an insulation supply store to find it.
What I would do if I were you is just line the interior with whatever insulation board you feel most comfortable with and then cover that with a loosely attached layer of Reflectix insulation or something like it. You can often buy it in small quanitity from hardware stores. It's the stuff that looks like bubble-wrap covered in aluminum foil. Tape all the seams with foil tape.
It's amazing stuff. Until recently I had my snakes in a 7'x7' room in an unheated, uninsulated garage. Two of the walls were exterior, the others were interior to the rest of the garage. The door was hollow-core. Again, all of the walls were hollow - no insulation.
I simply loosely stapled the Reflectix to the ceiling and walls and over the door. I wedged a piece of styrofoam across the bottom of the door opening to fill the > 1" gap.
I did nothing to the concrete floor - probably the worst area of heat loss in a garage.
So even during several days of -10* temperatures I was able to heat that room to 85* with my space heater set to 600 watts. In fact it still cycled on and off during this time.
I know we tend to get obsessed with R values but that terminology really only applies to forced-air heat. With radiant heat you have to think differently as it tends to more efficiently pass through traditional insulative barriers.
I don't know how crazy you want to get with this so I won't get into air spaces and all that.
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Current snakes:
0.2 Gonyosoma oxycephala - (Silver/Yellow)
3.3 Gonyosoma oxycephala - (Green)
2.1 Gonyosoma janseni - (Black)
3.3 Gonyosoma janseni - (Black & Tan)