I think your asking about such things as general shape, scale count, rib and vertabre count, tooth count and structure, etc. Yes there are differences, but unfortunately, sometimes they overlap. You can look up the differences, its been so long ago, I forget.
Sometimes with new types of reptiles, there is no way to really tell which group they fall into. So they are thrown into the most logical group, based on the above and locality. Later research will often reclassify them.
This was common back in the late sixties and early seventies, when we worked on many of the mexican montane kings. We would find questionable snakes and take them to the university to have them key them out. They often failed. For instance, we could find milksnake Tharyi and a from of milksnake in the exact same place.
After awhile we learned some very basic differences. And these had to do with behavior in captivity. For instance, montane kings copulate for 8 to 15 minutes(average) milksnakes copulate for 30 to 45 minutes, and getulus for over an hour up to 3 hours.
I am sure that now with all these crosses, this can be totally mucked up. But it served us well with wild caught kings and milks.
There are also types of kings and milks that were and are mis-identifyed. Again for instance, I had the first world Quererro king breeding. Except for the L.A. zoo, they had bred a snake they bred they called L.t.arcifera, which was not really arcifera, but instead ruthiveni(sorry for all the mis-spellings) Dalles zoo, was breeding the real milksnake, V.t.arcifera. They bred theirs before I did, but called it something else.
Also, the first Ruthivens king was discribed as an intermediate between milksnakes and montane kingsnakes. In reality is pure mountain king. By the way, I found the fifth thru the 27 ruthenvens king in 3 hours. Odd how animals can go unnoticed for so long. I hope this helps. FR