Well, I could show you a lot more than I could tell you on an online forum, unfortunately. I'll try to give you some advice.
-Find someone to teach you. To be safe, you really need to be with someone experienced until you learn what you are doing. Tubing a bull is a great start and how I got my practice (well, false water cobra). However, it's different when it's got fangs and venom.
-Tubing them while pinning the head won't work. They will just pull back when you release the head.
-Keep them in the bucket (well, see my next note...). They will try to go up the sides. When they do, put the tube JUST in front off them, but don't push it over them. Your best bet is to use the tube as their "escape route". Next thing you do is push the tube down over their body (light enough not to hurt, but firm enough not to let them escape). While you are lightly pinning them, firmly grab the mid body, right where the tube and body meet. If you feel it start to slip, just put the tube down and step away.
-I realized that the bucket will be burried in the ground. Bending all the way over and under the ground to pick up the tubed snake will be a little unreasonable. It is more dangerous and harder, but you may find that you'll need to tube on open ground.
-Stay out of strike range. It is easy to get distracted when tubing and step a little too close.
I've been tubing for the last three years. Sometimes it's easy and other times it is not. I had a cape cobra really give me a run for my money, but I finally got it. The more times you mess up with the same snake, the harder it will become. These guys catch on pretty quickly.
Now, scientifically, I have a concern with your methods. You'll be artifically selecting for any snake that can't escape from the bucket. In other words, only animals that fall for the trick are going to be included in the study. I agree that this is probably the only way to feasibly do this study, but you need to emphasize this in your discussion. Saying, for example, that species A is more likely to use these burrows than species B, based on evidence collected in the field, is misleading. At the end of that sentence, you'd have to include a disclaimer along the lines of, "of the animals caught in the traps" or something. Good sentence flow is gone by now for me. I've been at work for way too long. Just advising you to be cautious with your interpretation.
Good luck!!
Dave