I'd pick night adders, Causus, or a tiny Bitis, like caudalis or worthingtoni... Maybe the Fea's viper, Azimops, but I guess not much is known about it. Or maybe a copperhead if I were parked outside a hospital!
Anyway, that's my rather uninformed opinion... There's no 'good' viper to be bitten by, and they are ALL dangerous and ALL their bites are serious medical events. So I hope this was just a curiosity question rather than a basis for buying a pet. If you want a viper just to say you have a viper, buy a tricolored hognose and lie to your friends...