Welcome to the forum CritterChick!
Lots of very experienced and informed people lurk here. 
I will let someone else address the sexing, it is not overly difficult, and does not require a vet, though it is a little bit of an art form.
There is an excellent caresheet at http://www.deerfernfarms.com/Uromastyx_Care.htm that I highly recommend you read, it is one of the few that pretty much everyone on here agrees is good. 
The biggest problem I see is your tank size. There just is no way to create the proper temperature gradiant that the Uros need in a tank that small. (We are also discussing this down a few posts
). Their should be a hot spot somewhere between 115 and 120, but the uros also need to be able to thermoregulate, so you want a cooler side of the tank as well, at least to the low 90s. At night the tank can get even cooler, though I keep some heat on because I keep my house very cool.
The topic of feeding animal protein to the Uros has been widely debated, and you will hear various views. Depending on the age of your Uro feeding one a week may be ok. Juveniles can tolerate animal protein much better than the adult Uros can.
Are you also using a multivitamin powder? if not that would probably be a good thing to include. I use herptivite. The collard greens are a good choice to start, though you really want to rotate the greens as much as possible. Since I only have the one uro at this time, I rotate by bunch, buying a collard bunch - using it, then buying a different kind of green for the next week. Some of the greens, particularly collards, can bind calcium because their ratio is a little off, they are a good thing to include but you just don't want to feed them exclusively. 
It is so nice to know that you researched before buying your new friend, if more people did many Uros would have much easier lives! Now it is just time to continue on in the learning process. 
Welcome to the forum!
Elizabeth
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1.0 Mali Uro Archimedes (May he rest in peace)
0.0.1 Egyptian Uro Zuberi Mosca Khu (Mosca)
0.0 Fish
0.1 Sulcata Minnie
1.1 Iguanas Flik and Loki
0.1 Newfoundland Jasmine (RIP)
0.1 Feline Winter
Indiana & Wisconsin