You are on the right track in figuring out what you need to do on the business end of things. Being that every city, county and state have their own regulations, you will need to stay on that track for your area. But there are a number of other things to consider. You will also need to get a permit from California Fish & Game to catch and relocate native species. They may also require to you consult with biologists regarding where these snakes can be released to. Even if they don't require it, it is a good idea to talk to some biologists, either from the state or from your nearest university, so that you don't subject the snakes to a prolonged deaths. The subject of relocation is still a heavily debated one, but the general consensus at this point is that a snake relocated, or trans-located, over a mile away from the capture sight does not stand a good chance of finding adequate shelter and/or food. This increases the closer you get to the cooler, hibernation time of year. Also, there is the concern of potential disease/parasite transmission into different populations. Because of this, your state may not allow you relocate a snake outside of it's natural home range.
Aside from the biological implications, you also have to consider liability insurance. All it takes is one stupid mistake to cost you your car, home, life, etc…. I’m not so much talking about you being bitten because your not likely going to sue yourself (though that could be a costly mistake as well), but in the event someone else gets bitten, or injured, or if you step on their precious petunia’s and cause emotional distress (I know it seems funny, but worse things have happened). Also, you need to check with your car insurance because if you are using your vehicle for “business” use, you will likely be bumped to a different class.
These are just a few things I can recall right of the top of my head and 1 am. I don’t say these things to discourage you, although I must admit that it is discouraging at times. But once you get it all figured out and all your snakes in a row, it can be quite rewarding (though not very profitable).

Best of luck to you in your endeavors.

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